Putting QR codes in copper

Former Hackaday contributor [mikeysklar] has been trying to etch a QR code into a sheet of copper. Although his phone can’t read the CuR codes he’s made so far, he’s still made an impressive piece of milled copper.

The biggest problem [mikey] ran into is getting Inkscape to generate proper cnc tool paths instead of just tracing a bitmap image. He’s got the CNC part of his build under control, but he still can’t find a QR code reader that will register his work.

We’re no stranger to QR codes here at Hack a Day, and it’s very possible the only thing that could be stopping [mikey]’s QR code from being read by a phone is the contrast of the image. We’re thinking a little bit of printer’s ink forced into the non-copper part of the PCB would make the QR code register. Since [mikey] already has a very nice negative etching of his QR code, he could easily use his new board as a printing plate, making infinite paper copies of his copper-based QR code.

If you’ve got any ideas on how [mikey] can get his QR code working, post them in the comments.

Etching PCBs with vinegar

When we hear about etching PCBs at home we assume that either Ferric Chloride or Cupric Chloride were used to eat away unmasked copper from the boards. But [Quinn Dunki] just wrote up her PCB etching guide and she doesn’t use either of those. Instead, she combines vinegar, hydrogen peroxide, and salt. It’s easier to find vinegar than muriatic acid (Cupric Chloride is made using this, peroxide, and adding the copper) so this is something to keep in mind if you’re in a pinch (or a Macgyver situation).

The rest of the process is what we’re used to. She’s using photoresistant boards which can be masked with a sheet of transparency instead of using the toner-transfer method. Once they take a bath in the developer solution she puts them in a shallow dish of vinegar and hydrogen peroxide along with a teaspoon of salt. She wipes the surface with a foam brush every minute or so, and inspects them every ten minutes to see if they’re done.

She does discuss disposal. Seems that she throws the solution in the garbage after each use. The liquid will contain copper salts which are bad for wildlife. We’ve heard that you should neutralize the acid and make a block of concrete using the liquid, then throw it in the garbage. Does anyone have a well-researched, ethical, and environmentally friendly way of getting rid of this stuff?